Supplementary angles have measures with total of 180 degrees.
Let the angle's supplement be x
The other angle be 2x - 45
Equation:
x + 2x - 45 = 180
3x = 180 + 45
3x = 225
3x/3 = 225/3
x = 75
The angle's supplement, x ⇒ 75 degrees
The other angle, 2x 45 ⇒ 2 (75) - 45 = 105 degrees
The greater angle is 105 degrees.